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The Photochemical Reactivity of the “Photo-Inert” Tungsten (Fischer) Carbene Complexes

✍ Scribed by Israel Fernández; Miguel A. Sierra; Mar Gómez-Gallego; María J. Mancheño; Fernando P. Cossío

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
132 KB
Volume
118
Category
Article
ISSN
0044-8249

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A poly(o-trimethylsilylphenylacetylene) [poly(o-TMSPA)] initiated by a tungsten carbene complex was investigated under various conditions. The molar mass of poly(o-TMSPA) increases with increasing the polymerization temperature and decreasing the initiator concentration. The X-ray diffraction measur