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The Photochemical Conversions of Stilbenes to 9,10-Dihydrophenanthrenes

โœ Scribed by Sargent, M. V.; Timmons, C. J.


Book ID
126259368
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
286 KB
Volume
85
Category
Article
ISSN
0002-7863

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Photochemical conversion of poly-2,3-dip
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Poly-2,3-diphenylbutadiene dissolved in CH2C12 has been subjected to continuous irradiation at 313 nm and to flash photolysis at 266 nm at room temperature. Cyclization of pendant phenyl groups to dihydrophenanthrene groups dominates over isomerization, indicating impeded flexibility of polymer chai