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The photocatalytic autoxidation of sulfur oxoanions by water-soluble porphyrin complexes

✍ Scribed by Shen-Ming Chen


Book ID
104424044
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
384 KB
Volume
138
Category
Article
ISSN
1381-1169

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The catalytic and photocatalytic transformation of S 4 2-, S 3 2-, S 2 2-and S 2-to SO 4 2-by water-soluble cobalt tetrakis (N-methyl-4-pyridyl) porphyrin (Co(4-TMPyP)) was performed by a two-step process. The catalytic autoxidation of S x 2-(x = 2, 3 and 4) to S 2 O 3 2-by Co(4-TMPyP) in the presen

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Water-soluble manganese(II1) as well as iron(II1) porphyrinates are introduced as light-sensitive precursor compounds for the photocatalytic activation of dioxygen in aqueous solutions. It is shown that in the presence of a-pinene (4) and the further cycloalkenes 11 -13 photocatalytic oxygenation re