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The Photo-Fries Rearrangement

✍ Scribed by Miguel A. Miranda; Francisco Galindo

Publisher
John Wiley and Sons
Year
2003
Weight
47 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract The enol acetate **1b** undergoes benzoyl‐oxygen bond rupture upon irradiation, giving a mixture of benzophenones **4** and **5**. The primary photo‐Fries products **2** and **3** could not be isolated, due to a rapid intramolecular transacetylation. The acetophenone **6** rearranges to