Photolysis of [~-cydodextrin inclusion complexes of 1-and 2-naphthyi esters (acetates and benzeat~) in aqueous metfium, results in ~ to give one isomer of acylnaphthol in excess, whereas the solid state irra~ation of the Β’yclodextrin ~ yields soleftivety otlg isomer. In addition, formation of cleava
β¦ LIBER β¦
The photo-fries reaction of aryl esters: effect of solvent on production distribution
β Scribed by Don A. Plank
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 203 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The mechanism of the photo-Pries raarrangement of aryl esters has been investigated by a number of workers.(i) In this regard, it has been reported by some workers that the rearrange-
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## Abstract Enolβesters 1aβ1e undergo clean Photoβ__Fries__βrearrangements without side reactions. With anthroyl derivatives the reaction is observed only at 254 nm, not at 366 nm.
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