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The Phenoxyl Radical–Water Complex—A Matrix Isolation and Computational Study

✍ Scribed by Sander, Wolfram; Roy, Saonli; Polyak, Iakov; Ramirez-Anguita, Juan Manuel; Sanchez-Garcia, Elsa

Book ID
111649762
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
775 KB
Volume
134
Category
Article
ISSN
0002-7863

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✍ Artur Mardyukov; Rachel Crespo-Otero; Elsa Sanchez-Garcia; Wolfram Sander 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 595 KB

## Abstract The reaction of the phenyl radical **1** with water has been investigated by using matrix isolation spectroscopy and quantum chemical calculations. The primary thermal product of the reaction between **1** and water is a weakly bound complex stabilized by an OH⋅⋅⋅π interaction. This com