## Abstract It has been shown that pH\* values, determined by the electrometric method in solvents other than water, can be interpreted as ‐log __m__~H~γ\*~H~ if the pH meter is standardized by means of a standard solution in the same solvent. The pH\* of standard solutions in methanol and methanol
The pH of some standard solutions in methanol and methanol-water mixtures at 25° II. Experimental Part
✍ Scribed by C. L. de Ligny; P. F. M. Luykx; Miss M. Rehbach; Miss A. A. Wieneke
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 563 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0165-0513
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
By application of a method which was developed in Part I of this series the pH* of an oxalate and a succinate buffer in water, methanol‐water mixtures and methanol and that of a salicylate buffer in methanol was measured. The pH* in methanol was measured by application of both silver chloride and silver bromide electrodes: the values obtained agreed closely.
📜 SIMILAR VOLUMES
## Abstract The determination of the liquid‐junction potential at the interface of an oxalate and a succinate buffer solution of known pH\* in water, methanol or a methanol‐water mixture and a saturated KCl solution in water at 25° is described. When the pH\* of such a solution is measured by means
The dissociation constants and the molar conductivitis at the limit of zero concentration of 5nitro-, khloro-and 5-bromosalicyclic acids have been determined in water-methanol mixtures at 25°C. The experimental data have been analysed with the Lee and Wheaton conductance equation.