𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The pH Dependence of the Mechanism of Reaction of Hydrogen Peroxide with a Nonaggregating, Non-μ -oxo Dimer-Forming Iron(III) Porphyrin in Water

✍ Scribed by Thomas C. Bruice, Matthias F. Zipplies and William A. Lee


Book ID
123632893
Publisher
National Academy of Sciences
Year
1986
Tongue
English
Weight
572 KB
Volume
83
Category
Article
ISSN
0027-8424

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Kinetic simulation studies on the transi
✍ Tapan Kumar Saha; Subarna Karmaker; Keietsu Tamagake 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 279 KB 👁 3 views

High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o