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The perturbation spectrum of CO

✍ Scribed by T.G. Slanger; G. Black


Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
282 KB
Volume
4
Category
Article
ISSN
0009-2614

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✦ Synopsis


Irradiation of CO by CO Fourth-Positive light results in emission from various CO triplet states, and this emission is attributed to a rcsonnnce fluorescence process involving optically forbidden transitions. Certain rotational levels of the triplet states are perturbed by the A1 II state, and it is only these levels that. are seen in emission.


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TABLE 1 Observed Transitions in the Spectrum of HCCH-CO (in cm ؊1 ) a a This transition not observed; the value in parentheses is the calculated position. b These lines were omitted from the fit (see text). TABLE 2 Molecular Parameters for HCCH-CO (in cm ؊1 ) Note. 1 uncertainties are in parenthese