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The Persistent Radical Effect in Nitroxide Mediated Polymerization: Experimental Validity

✍ Scribed by Jean-François Lutz; Patrick Lacroix-Desmazes; Bernard Boutevin

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
111 KB
Volume
22
Category
Article
ISSN
1022-1336

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The persistent radical effect in control
The persistent radical effect in controlled radical polymerizations
✍ Hanns Fischer 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB 👁 1 views

We describe the basic kinetic features of "living" polymerizations controlled and regulated by persistent radicals or related species and by reversible atom transfer. In these systems a special kinetic phenomenon operates-the Persistent Radical Ef-fect. It is also known from selective organic synthe