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The Peroxy Acid Dioxirane Equilibrium: Base-Promoted Exchange of Peroxy Acid Oxygens

✍ Scribed by Porter, Ned A.; Yin, Huiyong; Pratt, Derek A.


Book ID
120262277
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
33 KB
Volume
122
Category
Article
ISSN
0002-7863

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## Abstract The spiro transition state for the oxygen transfer by dioxiranes is substantiated by the fact that no enhanced steric effects are observed when dioxiranes with alkyl groups of different size are employed, as manifested by the same (within the experimental error) diastereoselectivities i