✦ LIBER ✦

The permanent dipole moment of ScF

✍ Scribed by Benoit Simard; Michael Vasseur; Peter A. Hackett

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 431 KB
Volume: 176
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)90034-7

No coin nor oath required. For personal study only.

✦ Synopsis

The permanent electric dipole moment of ScF in its X 'C+ and C '2' electronic states has been determined in a pulsed molecular beam apparatus by measuring the Stark shifts on the P( I ) and R( 0) lines of the (0,O) band of the C 'Z+-X 'Et system.

Values of 1.72 (2) and 2.60( 5) D have been derived for the X 'I;+ and C 'Z+ states, respectively. These values are compared with ab initio data and rationalized in terms of the leading electronic configurations giving rise to the states.

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