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The parent of 2-(4,5-dihydro-1H-tetrazol-5-ylidene)-2-cyanoacetate: Synthesis and reactivity X-ray structure of (E)2-[1-(2,2-dimethylpropyl)-4,5-dihydro-1H-tetrazol-5-ylidene]-2-cyanoacetate

✍ Scribed by Rolf W. Saalfrank; Claus-Jürgen Lurz; Uwe Wirth; Hans Georg Von Schnering; Karl Peters


Book ID
112130188
Publisher
Journal of Heterocyclic Chemistry
Year
1991
Tongue
English
Weight
421 KB
Volume
28
Category
Article
ISSN
0022-152X

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-vlidene derivatives 1-3 with primary and secovdary alkylarmnes in CH,CL at room temperature gave 2,5-dzhydro-2-iminopyrroles (22-55%) and 2, 5-dihydro-2-imino[urans (18-62%). However, similar treatment of alltyl (4-chloro-5H-1,2,3dithtazol-5-ylidene)cyanoacetates under the same conditions gave (Z)-