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The palladium–phenanthroline catalyzed carbonylation of nitroarenes to diarylureas: Effect of chloride and diphenylphosphinic acid

✍ Scribed by Michela Gasperini; Fabio Ragaini; Chiara Remondini; Alessandro Caselli; Sergio Cenini

Book ID
108188047
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
202 KB
Volume
690
Category
Article
ISSN
0022-328X

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✍ Fabio Ragaini; Michela Gasperini; Sergio Cenini; Lucia Arnera; Alessandro Casell 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 368 KB 👁 1 views

## Abstract Palladium–phenanthroline complexes catalyze both the nitroarene carbonylation reaction and the amine oxidative carbonylation reaction to give, depending on the conditions, carbamates and ureas. There is evidence that the key step in both processes is the amine carbonylation. Here, we sh