𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The palladium catalyzed allylic alkylation of bis(trimethylsilyl) substituted propenyl acetates or carbonates in the presence of chiral ligands

✍ Scribed by Donna L. Romero; Edward L. Fritzen

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
199 KB
Volume
38
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Palladium catalyzed asymmetric allylic alkylations of a bis(trimethylsilyl) substituted propenyl acetate and carbonate were investigated using various chiral ligands and reaction conditions. The best enantioselectivity (86% e.e.) was obtained with the substrate l-phenyl-3,3-bis(trimethylsilyl)propenyl carbonate 13 and the chiral oxazoline ligand 4c.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Palladium-Catalyzed
ChemInform Abstract: Palladium-Catalyzed Asymmetric Allylic Alkylation in the Presence of a Chiral β€œLight Fluorous” Phosphine Ligand.
✍ Marco Cavazzini; Gianluca Pozzi; Silvio Quici; David Maillard; Denis Sinou πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 27 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Asymmetric allylic alkylation using a po
Asymmetric allylic alkylation using a polymer-supported palladium catalyst in the presence of chiral ligands
✍ Maria Michela Dell’Anna; Piero Mastrorilli; Cosimo Francesco Nobile; Gian Paolo πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 80 KB

Polymer-supported Pd(AAEMA) 2 (Pd-pol) [AAEMA -: deprotonated form of 2-(acetoacetoxy)ethyl methacrylate] in the presence of chiral ligands catalyses the asymmetric substitution of rac-1,3-diphenyl-2-propenyl acetate with dimethyl malonate. A series of conventional ligands were tested: the enantiose