10 : I), 15 equiv. Br2), selectively furnishes the dibromoketone 19b (yield ca. 85%); a preparatively very useful['31 stereofacial selectivity manifests itself in the regiospecific cleavage of the syn-ether on the "open" side of the dibromide 18b. The elimination of bromine from 19b to give the biss
✦ LIBER ✦
The Pagodane Route to Dodecahedranes: Polyfunctionalized Homologous Dodecahedranes and Dodecahedrenes
✍ Scribed by Dipl.-Chem. Rolf Pinkos; Dipl.-Chem. Johann-Peter Melder; Prof. Dr. Hans Fritz; Prof. Dr. Horst Prinzbach
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 454 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
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The energy-rich C2,H2, hydrocarbon I1 .l.l.l]pagodane A (X = Y = H)"] can be converted into dodecahedrane B (X = Y = Z = H) catalytically[21 as well as stepwise (via C, D and E).['] The yields of these procedures, yet encouraging in view of the ready availability of the starting materials, remain un
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