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The oxygenation of cyclopalladated N,N-dimethylbenzylamine derivatives with tert-butyl hydroperoxide

✍ Scribed by Paul L. Alsters; Herman T. Teunissen; Jaap Boersma; Gerard van Koten

Book ID
104589231
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
184 KB
Volume
109
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

Cyclopalladated N,N‐dimethylbenzylamine complexes can be oxygenated with tert‐butyl hydroperoxide to the corresponding phenolates in good yield (> 80%); the rate of oxygenation is highly enhanced by increasing the nucleophilicity of the metal center or by addition of a vanadium catalyst.

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