✦ LIBER ✦

The oxime rearrangement cyclization. Alkenyl, styryl and vinyl chloride terminators in the synthesis of Δ1-pyrrolines

✍ Scribed by Robert E. Gawley; Enrico J. Termine

Book ID: 104220316
Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 137 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)86816-1

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✦ Synopsis

Punctionalized y,6 -unsaturated oximes, constructed by regiospecific alkylation of appropriate oximes, may be rearranged and cyclized to AI-pyrrolines in good yield.

The cationic cyclization of nitrilium ions to form Al-pyrrolines has been known for some time.

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