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The Oxide Ba6Ga2Co11O26: A New Close-Packed Stacking Derived from the Hexagonal Perovskite.

✍ Scribed by D. Pelloquin; O. Perez; G. Martinet; S. Hebert; A. Maignan

Publisher
John Wiley and Sons
Year
2007
Weight
13 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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The n=2 Member of the New Layered Struct
The n=2 Member of the New Layered Structural Family Ba5+nCa2Mn3+nO3n+14 Derived from the Hexagonal Perovskite: Ba7Ca2Mn5O20
✍ N. Floros; C. Michel; M. Hervieu; B. Raveau πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 English βš– 426 KB

A new manganese oxide Ba 7 Ca 2 Mn 5 O 20 , with an original structure derived from the 21 L hexagonal perovskite, has been synthesized and studied by XRPD and HREM. This rhombohedral phase (R % 3m), with a ¼ 5:8207ð2Þ ( A and c ¼ 51:359ð1Þ ( A, consists of [BaO 3 ] (h and c) layers and [BaO 2 ] (c