The oxidative part of the glucose-oxidase reaction
✍ Scribed by Vladimir Leskovac; Jasmina Svirčević; Mirjana Radulović
- Book ID
- 103120470
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 587 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0020-711X
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## Abstract The kinetics of oxidation of glucose solution by dissolved oxygen in the presence of glucose oxidase and excess catalase were studied both theoretically and experimentally. The kinetic model used was based on the detailed mechanism of the reaction. The description of the model is given
A quantum-chemical model for electrostatic effects (QCMEE) in biomolecules is applied to the reductive half-reaction of glucose oxidase. The electrostatic influence of the enzyme on its active center is estimated. Six different states of protonation of the active center are compared by a hybrid meth