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The oxidative fragmentation of 1-amino-1,3,4-triazoles to nitrogen and nitriles

✍ Scribed by K. Sakai; J.-P. Anselme


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
179 KB
Volume
11
Category
Article
ISSN
0040-4039

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A thermal fragmentation of 1,2,4-oxadiaz
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1,2,4-Oxadiazole-4-oxides undergo clean thermal cleavage in refluxing chlorobenzene or xylene to nitriles and nitrosocarbonyl intermediates, which are either trapped with suitable olefins to afford ene adducts or dimerize and rearrange to anhydrides.