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The oxidative coupling of vinyl acetate with palladium acetate; synthesis of 1,4-diacetoxy-1,3-butadiene

✍ Scribed by C. F. Kohll; R. van Helden


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
494 KB
Volume
86
Category
Article
ISSN
0165-0513

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A general, highly selective route to skipped (1,4) diynes, including the hitherto unknown 3-substituted derivatives, is provided by the reactions of (propargyl acetate)Co2(C0)6 complexes with trialkynyl alanes and subsequent demetallation.