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The Oxidation Reactions of Peroxydiphosphate. I. The Kinetics and Mechanism of the Reaction with Tris (1,10-phenanthroline) iron (II)

✍ Scribed by Green, Agnes Ann; Edwards, John O.; Jones, Peter


Book ID
125450630
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
577 KB
Volume
5
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of silver(I) cata
✍ P. Parasher; J. Hussain; P. D. Sharma πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 471 KB

A kinetic study of the silver(1)-catalyzed oxidation of tris(1,lO-phenanthroline)iron(II) with peroxodiphosphate was carried out by estimating tris-complex at 510 nm. The reaction is found to conform to the rate law (i). with K2 and K3 being the acid dissociation constants of H~P208-and H~Pz082-, r