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The Oxidation of Thebaine with m-Chloroperbenzoic Acid. Studies in the (+)-Morphinan Series. III

✍ Scribed by Ikuo Iijima; Kenner C. Rice; Arnold Brossi

Publisher
John Wiley and Sons
Year
1977
Tongue
German
Weight
160 KB
Volume
60
Category
Article
ISSN
0018-019X

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✦ Synopsis

Zur Oxydation von Thebain mit m‐Chlorperbenzoesäure, III

Die Oxydation von Thebain (1) mit m‐Chlorperbenzoesäure ist stark abhängig von den gewählten Reaktionsbedingungen. In unserem Fall wird neben 14‐Hydroxy‐codeinon (2) auch das bekannte, mono‐acetylierte Diol 3 erhalten. Die Rückführung von 3 in 2 und die Verknüpfung mit dem bekannten Ketodiol 5, über das bisher nicht beschriebene 8, 14‐Dihydroxydihydrothebain (4) wird gezeigt.

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