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The oxidation of cerous ions by bromate ions comparison of experimental data with computer calculations

✍ Scribed by S. Barkin; M. Bixon; R. M. Noyes; K. Bar-Eli

Publisher: John Wiley and Sons
Year: 1977
Tongue: English
Weight: 897 KB
Volume: 9
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550090514

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✦ Synopsis

Abstract

The oxidation of cerous ions by bromate ions in sulfuric acid medium was followed spectrophotometrically under various experimental conditions. The results were compared to the calculated predictions on the basis of a mechanism suggested by R. M. Noyes and collaborators. The computations were done by solving the complete set of the kinetic differential equations. The results of the computations show that the proposed mechanism explains adequately most of our and previous experimental data. In particular, the mechanism predicts the main features of the reaction, namely, the induction and the fast and slow reaction periods which occur during the oxidation.

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