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The oxidation of 9:10 diketostearic acid by peracetic acid (baeyer and villiger reaction)

โœ Scribed by D. N. Grindley; S. A. El Sarrag

Book ID
112805508
Publisher
Springer-Verlag
Year
1972
Tongue
English
Weight
115 KB
Volume
49
Category
Article
ISSN
0003-021X

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Oxidation of 2 with m-chloroperbenzoic acid in the presence of SnCI4 at -78 ยฐC followed by hydrolysis afforded optically active 4 in a quantitative yield. The enantiomeric excess (ee) of 4 largely depended on the reaction solvent, the chiral diol part, the Lewis acid and its amount. The best ee was