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The overlap component of the stereoelectronic factor. Remote control of stereogenicity transfer through the anisotropic influence of a ring

✍ Scribed by Berson, Jerome A.


Book ID
126106939
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
932 KB
Volume
24
Category
Article
ISSN
0001-4842

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Transfer of substituent influence into t
✍ V. F. Loktev; I. L. Mudrakovsky; A. K. Tashmukhamedova; I. A. Stempnevskaya; I. πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 209 KB

## Abstract ^13^C NMR studies of 4′‐R‐dibenzo‐18‐crown‐6 and 4′‐R‐dibenzo‐24‐crown‐8 showed that the substituent influence is transferred through the macrocycle to a remote aromatic ring. The transfer is due to steric effects and depends on crown ether complex formation.