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The out-of-plane ring deformations of 1,3- and 1,4-dioxene and 3,6-dihydro-2h-pyran: comparison of a series of cyclohexenes

✍ Scribed by E.A. Dixon; G.S.S. King; T.L. Smithson; H. Wieser


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
823 KB
Volume
71
Category
Article
ISSN
0022-2860

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Optimized geometries and energies for 3,4-dihydro-1,2-dithiin Ε½ . Ε½ . Ε½ . Ε½ . 1 , 3,6-dihydro-1,2-dithiin 2 , 4H-1,3-dithiin 3 , and 2,3-dihydro-1,4-dithiin 4 were calculated using ab initio 6-31G U and MP2r6-31G U rr6-31G U methods. At the MP2r6-31G U rr6-31G U level, the half-chair conformer of 4