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The origin of the sulfone in photooxidations involving sulfurane intermediates

✍ Scribed by Edward L. Clennan; Kang Yang

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
371 KB
Volume
4
Category
Article
ISSN
1042-7163

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✦ Synopsis

The photooxidations of y-hydroxysulfides which give abnormally high ,yields of sulfones have been investigated. This unusual result is attributed to the potent trapping ability of a hydrogen bonded sulfoxide intermediate. This suggestion is supported by measuring the ability of a y-hydroxysulfoxide to trap the persulfoxide formed in the photooxidation o f diethyl sulfide and by ca.veful analysis of the reaction composition as a function of time.

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