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The origin of the [M – 1]+ ion in the mass spectra of N,N-dialkylbenzamides. A reinvestigation of the mechanism

✍ Scribed by C. W. Fong; C. R. Hameister

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
399 KB
Volume
13
Category
Article
ISSN
1076-5174

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✍ J. M. Buschek; J. J. Ridal; J. L. Holmes 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 642 KB

The collisional activation (CA) mass spectra of the two isomeric [C,H,]+ ions, benzyl and tropyl, have been reassessed. The structurecharacteristic feature of their CA mass spectra, the m/z 77:74 abundance ratio, has been confirmed as 3.15 f 0.2 for benzyl cations and lowered to 035 f 0.3 for tropyl