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The origin of kinetic cooperativity in prehiotic catalysts

✍ Scribed by Jacques Ricard; Jacques Vergne; Jean-Luc Decout; Marie-Christine Maurell


Book ID
105537988
Publisher
Springer
Year
1996
Tongue
English
Weight
781 KB
Volume
43
Category
Article
ISSN
0022-2844

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The origin of cooperativity in high-spin
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A new model for the first-order transitions between the low-spin and high-spin phases of molecular crystals of some transition metal complexes is proposed. Tbe abrupt spin transitions (or those exhibiting thermal hysteresis) are attributed to first-order transitions between the different crystal pha