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The Origin of Hindered Rotation around the Pt−N Bond in Platinum Amides

✍ Scribed by Albéniz, Ana C.; Calle, Virginia; Espinet, Pablo; Gómez, Sandra

Book ID
126035408
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
120 KB
Volume
40
Category
Article
ISSN
0020-1669

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Dynamic NMR study of hindered rotation around the CN bond in thiopiperidides
✍ Mariana Ciureanu; Victor E. Sahini; Felicia Cornea; Cornelia Cercasov; Mihai Con 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 356 KB 👁 1 views

## Abstract The barriers to internal rotation about the CN bond in several thiopiperidides have been determined by the NMR technique. It was found that the barrier height (Δ__G__^‡^) increases in the series cinnamoylthiopiperididem‐and __p__‐substituted cinnamoylthiopiperidides the barriers were s