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The origin of Felkin–Anh control from an electropositive substituent adjacent to the carbonyl group †

✍ Scribed by Fleming, Ian; Hrovat, David A.; Borden, Weston Thatcher

Book ID
120316968
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
896 KB
Volume
3
Category
Article
ISSN
1472-779X

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Hydrazine reacts smoothly v&h sugars having a glycosidic SubstiNent when the glycosyl moiety is located on a carbon atom adjacent to au aldehyde or lceto group. resulting in cleavage of the glycosidic linkage. In excess hydrazine. the released glycoside forms a hydrazone from which the reducing suga