The orientation of the dipole change for the OH stretch in methanol and nitric acid
β Scribed by B.J. van der Veken; W.A. Herrebout; H.H. Liefooghe
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 853 KB
- Volume
- 268
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The polarographic reduction of uranyl ion in nitric acid solution are found to be one electron reduction mechanism at lower acid concentration (0.1 M HNO,) and two electron mechanism at high acid concentration (2 M HNO,). Methanol shifted the half wave potentials to more negative values and increase
The absorption spectrum of methanol vapor has been recorded at room temperature from 3200 to 4200 cm Οͺ1 with a 1.24-M path-difference Fourier transform spectrometer. Over 10 000 transitions to the torsion-rotation states n, J, K of the OH stretching fundamental band 1 have been assigned, thereby gre
data. frorii &$+ys solutidri~~ we define,.these rati& ,:,but"mono'acidic. Thus; for Mgit, the influence of the (Q') by:,' '-'-,' ., '. ,: ,. '. '. ,. cation-oxygen 'bonds upon the btr>hs of the hydrogen bonds f&med by coordinated water molecules, '01 jj6!SNn' .-' : Es' .( (I)-,-' .
## Abstract The oxidation of methanol in a flow reactor has been studied experimentally under diluted, fuelβlean conditions at 650β1350 K, over a wide range of O~2~ concentrations (1%β16%), and with and without the presence of nitric oxide. The reaction is initiated above 900 K, with the oxidation