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The Organic Chemistry of Enzyme Catalyzed Reactions. Richard B. Silverman

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
15 KB
Volume
291
Category
Article
ISSN
0003-2697

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The reactions of metastable CH,-CHCH=bCH, oxonium ions generated by alkyl radical loss from ionized allylic alkenyl methyl ethers are reported aod d i s c d Three main reactions occur, corresponding to expulsion of H,O, C2H,/C0 and CH,O. There is also a very minor amount of C,H, elimination. The mec