The Order of Reactivity of Dienes towards Maleic Anhydride in the Diels-Alder Reaction
✍ Scribed by Dr. J. Sauer; D. Lang; A. Mielert
- Publisher
- John Wiley and Sons
- Year
- 1962
- Tongue
- English
- Weight
- 215 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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Grafting reactions were performed in a Haake torque rheometer, according to a central composite experimental design, where the maleic anhydride and peroxide concentrations, rotor speed, and reaction time were varied. The 27 formulations were analyzed by Fourier transformed infrared spectroscopy and
In the presence of a strong Lewis base, such as Et 3 N, trithio-1,8-naphthalic anhydride ( 3) is easily oxidized. Two improved syntheses of trithio-1,8naphthalic anhydride (3) are described. Trithio-1,8-naphthalic anhydride (3) undergoes Diels-Alder reactions with electron-deficient alkenes to give