THE OBSERVATION OF REARRANGEMENT DURING HYDROGENOLYSIS; A NEW METHOD OF PREPARING BRIDGEHEAD CARBOXYLIC ACIDS
β Scribed by Kwart, Harold; Null, George
- Book ID
- 126974492
- Publisher
- American Chemical Society
- Year
- 1958
- Tongue
- English
- Weight
- 252 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Reaction of 2,4-dinitrobenzenesulfonamide with acyl chlorides in the presence of excess triethylamine produces the corresponding nitrile in good to fair yields. Mechanistic studies indicate that the reaction proceeds via a Smiles rearrangement of the initially formed N-(2,4dinitrohenzenesulfonyl)ami
Seoul 131, Korea Reaction of carboxylic acids with equimolar amounts of alkyl chloroformate and triethylamine in the presence of a catalytic amount of 4-dimethylaminopyridine affords the corresponding esters in high yields without the formation of the symmetrical anhydride in most carboxylic acids.