The nucleophilic efficiency of remote cyclopropane in intramolecular displacement reactions: Synthesis and acetolysis of 2-(trans-3- bicyclo[3.1.0]hexyl)-ethyl p-nitrobenzenesulfonate

The nucleophilic efficiency of remote cy

The nucleophilic efficiency of remote cyclopropane in intramolecular displacement reactions: synthesis and acetolysis of 2-(trans-3-bicyclo[3.1.0]) Ethyl p-nitrobenzenesulfonate

✍ G.Dann Sargent; Robert L. Taylor; Wolfgang H. Demisch 📂 Article 📅 1968 🏛 Elsevier Science 🌐 French ⚖ 290 KB

Over the past two decades, increasing attention has been devoted to the nucleophilicity of carbon-carbon bonding electrons. Essentially four types of nucleophile within this class have emerged: aromatic pi electrons, (l-3) carbon-carbon double bonds, (1.2,h) cyclopropane carbon-carbon 8igm bonds, (1