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The normal coordinate analysis of porphin and its derivatives based on the solution of the inverse spectral problem for porphin and Cu porphin—II. A valence force field for in-plane vibrations of the Cu porphin molecule

✍ Scribed by L.L. Gladkov; K.N. Solovyov

Book ID
108007255
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
484 KB
Volume
41
Category
Article
ISSN
1386-1425

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The normal coordinate analysis of porphi
The normal coordinate analysis of porphin and its derivatives based on the solution of the inverse spectral problem for porphin and Cu porphin—I. A valence force field for in-plane vibrations of the porphin molecule
✍ L.L. Gladkov; K.N. Solovyov 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 620 KB

The inverse spectral problem for porphin is solved by the regularized least squares method. For determining 30 force constants related to in-plane molecular vibrations, 256 frequencies of porphin and its four deuteratcd derivatives are used. The form of the porphin molecule vibrations is discussed.