The Nonclassical Ion Problem

✍ Scribed by Herbert C. Brown (auth.)

Publisher: Springer US
Year: 1977
Tongue: English
Leaves: 311
Edition: 1
Category: Library

No coin nor oath required. For personal study only.

✦ Table of Contents

Front Matter....Pages i-xxii
That Fascinating Nonclassical Ion Problem....Pages 1-19
Steric Assistance in Solvolytic Processes....Pages 21-33
σ-Participation — A Factor in Fast Rates?....Pages 35-46
Carbon — Bridged Cations....Pages 47-68
The Cyclopropylcarbinyl Cation....Pages 69-82
The 2-Norbornyl Cation....Pages 83-100
Stabilized 2-Norbornyl Cations....Pages 101-122
Exo : Endo Rate Ratios as a Steric Phenomenon....Pages 123-149
Equilibrating Tertiary 2-Norbornyl Cations....Pages 151-161
Effect of Increasing Electron Demand....Pages 163-186
Substituent and Structural Effects in 2-Norbornyl....Pages 187-218
Capture of Unsymmetrical 2-Norbornyl Cations....Pages 219-235
Equilibrating Cations under Stable Ion Conditions....Pages 237-259
New Concepts—New Systems....Pages 261-281
Final Comments....Pages 283-289
Epilog....Pages 291-292
Back Matter....Pages 293-301

✦ Subjects

Characterization and Evaluation of Materials

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