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The Non-planarity of 2- t -Butyl-3,7,7-trimethyltropilidene

โœ Scribed by Conrow, Kenneth.; Howden, Merlin E. H.; Davis, Donald.


Book ID
127233234
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
720 KB
Volume
85
Category
Article
ISSN
0002-7863

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Non-planar axial Me2N in cis-2-dimethyla
โœ M.Gary Newton; Nantelle Pantaleo; Wesley G. Bentrude; S. Chandrasekaran ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 247 KB

An X-ray crystallographic study of the Summary: title compound shows it to have an axial Me2N with pyramidal N and a lengthened N-P bond. Conversely, the endocyclic NH-P bond is shortened. The origins of these effects are assigned to specific geometrical relationships of the Me2N/P=S and NH/P=S grou