✦ LIBER ✦

The NMR spectrum and total geometry of selenophene determined in the liquid crystal medium ZLI 1167

✍ Scribed by William Bechtold; G. Brock Magruder; J. H. Goldstein

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 299 KB
Volume: 19
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270190402

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✦ Synopsis

Abstract

The calculated ^12^C, ^13^C and ^77^Se spectra of selenophene have been reproduced from the observed proton NMR spectrum in the orienting medium Merck ZLI 1167, and the entire ring structure computed. The effects on structure of vibration, solvent dependence of couplings and temperature have been explored. Most notable was the observation of a substantial increase in the SeC bond length, comparable to that previously reported for selenophene in Merck Phase IV.

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