✦ LIBER ✦

The Nitrosation of Primary Aliphatic Diazocarbonyl Compounds: Formation of α-carbonyl nitrile oxides. Preliminary communication

✍ Scribed by Hans Dahn; B. Favre; J.-P. Leresche

Book ID: 102251357
Publisher: John Wiley and Sons
Year: 1973
Tongue: German
Weight: 258 KB
Volume: 56
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19730560136

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✦ Synopsis

Abstract

Aqueous nitrosation of primary α‐carbonyl diazo compounds (ethyl diazoacetate, diazoacetone, diazoacetophenones) yields α‐carbonyl nitrile oxides, RCOCNO; their formation is demonstrated by 1,3‐dipolar addition reactions.