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The NH(C)Br functionality of heteroaromatic compounds as a synthon for fused dihydrooxazoles

✍ Scribed by Marek T. Cegla; Marzena Baran; Agnieszka Czarny; Marek Zylewski; Joanna Potaczek; Jeff Klenc; Lucjan Strekowski

Publisher
Journal of Heterocyclic Chemistry
Year
2011
Tongue
English
Weight
88 KB
Volume
48
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

Fused dihydrooxazoles are produced by the reaction of 8‐bromoteophylline (1), 6‐bromo‐2‐pyridone (7), or 2‐bromobenzimidazole (11) with an N‐substituted N‐(2,3‐epoxypropyl)amine. The product derived from 1 undergoes rearrangement to a fused dihydrooxazine while the fused dihydrooxazoles derived from 7 and 11 are stable. J. Heterocyclic Chem., (2011).

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