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The new molecule 1-cyano-4-phosphabutadiyne, NCCCCP, produced by copyrolysis of PCl3 and CH3CCCN: Detection and vibration-rotation analysis by microwave spectroscopy

✍ Scribed by M.C. Durrant; H.W. Kroto; D. McNaughton; J.F. Nixon


Book ID
107802277
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
472 KB
Volume
109
Category
Article
ISSN
0022-2852

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✍ M.J. Hopkinson; H.W. Kroto; J.F. Nixon; N.P.C. Simmons 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 175 KB

The reactive molecule I-phosphapropyne, CHJt%P, which is the phosphorus analogue of methylcyanide CH&N, has been detected by microwave spectroscopy in the pyrolysis products of ethyldichlorophosphine CHaCHaPCla. The J = 3 +-2 and J = 4 + 3 sy\_mme?ric top transitions have been assigned and a value o