The nd1Δg (n=11-15) Rydberg States of K2 Studied by Optical-Optical Double Resonance Spectroscopy and Space Charge Limited Diode Ionization Detector
✍ Scribed by J.T. Kim; C.C. Tsai; H. Wang; J.T. Bahns; W.C. Stwalley
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 394 KB
- Volume
- 172
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
Five bound (n d^{1} \Delta_{g}(n=11-15)) electronic states have been investigated using optical-optical double resonance excitation followed by ionization detection using an ultrasensitive space charge limited diode, which detects ion signals (presumably (\mathrm{K}{3}^{+})produced by associative ionization). The molecular constants and the Rydberg-Klein-Rees potential curves for these states have been generated. The dissociation energies, additional binding energies, and molecular constants due to the weakly bound Rydberg bonding (\delta{8}) orbitals are discussed. 1995 Academic Press, Inc.