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The nature of the superoxide ion in dipolar aprotic solvents:: The electron paramagnetic resonance spectra of the superoxide ion in N,N-dimethylformamide — evidence for hydrated forms

✍ Scribed by Martin R. Green; H. Allen; O. Hill; David R. Turner

Book ID
115910420
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
406 KB
Volume
103
Category
Article
ISSN
0014-5793

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## Abstract Absorption spectra of the superoxide ion have been studied in dimethylformamide (DMF) and acetonitrile (AN). It was found that the superoxide ion existed in equilibrium with an ion pair in AN (__K__~eq~ = 20__M__^−1^, Bu~4~N^+^ is the cation) and as “free” (solvated) ion in DMF. The add