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The nature of the P–P bond in carbene-stabilized diphosphorus complex

✍ Scribed by Liu, Z.

Book ID
125369397
Publisher
Springer
Year
2013
Tongue
English
Weight
462 KB
Volume
25
Category
Article
ISSN
1040-0400

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Hydrolysis of phosphinamides and the nat
Hydrolysis of phosphinamides and the nature of the PN bond
✍ Paul Haake; Toru Koizumi 📂 Article 📅 1970 🏛 Elsevier Science 🌐 French ⚖ 204 KB

Carboxylic amides are quite stable towards chemical hydrolysis; elevated temperatures and high concentrations of acid or base are required for appreciable rates of hydrolysis. Yet, amides of phosphoric acid appear to be highly reactive. Phosphoramidate (&) is a reactive ' was obtained at 90°C; k, f