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The nature of the O—O bond in hydroperoxides

✍ Scribed by K. A. Lysenko; M. Yu. Antipin; V. N. Khrustalev

Book ID
110318284
Publisher
Springer
Year
2001
Tongue
English
Weight
404 KB
Volume
50
Category
Article
ISSN
1573-9171

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## Abstract A survey of 42 germanates has revealed that the bond lengths of the GeO~4~ groups linearly decrease with increasing the Ge–O–Ge angles on account of the increase of __π__-bond character between Ge and O atoms. The amount of __π__-bond character which gives rise to the Ge–O bond shorteni