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The nature of the long-wave bands in the emission spectra of aromatic o-hydroxycarboxylic acids and their derivatives

✍ Scribed by B. A. Zadorozhnyi


Publisher
Springer US
Year
1966
Tongue
English
Weight
332 KB
Volume
5
Category
Article
ISSN
0021-9037

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## Abstract Acylation of allyl alcohols induces strong carbon shifts, shielding Ξ³ and deshielding Ξ΄ effects. These shifts are a consequence of through‐bond polarization of the olefinic carbons. Allyl ethers show similar, but milder perturbations. The olefinic carbon shifts reveal a strong concentra